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Category:2001 films
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Category:Films about surrogacyStability and solubilizing effects of phosphatidylcholine derivatives on the naturally-occurring flavonoid quercetin.
The effects of esterification of quercetin with phosphatidylcholine by various phospholipase D (PLD) catalysts and phospholipase C (PLC) catalysts on the stability and solubility of the flavonoid were studied in aqueous buffer at pH 7.4 and 25 degrees C. The derivatives were obtained from 1-O-acyl-sn-glycero-3-phosphocholine catalyzed by either lysophospholipase D (lyso-PLD) or phospholipase C (PLC). Of the products formed from lyso-PLD and PLC catalysts, quercetin-1-palmitate was the most stable at pH 7.4. Quercetin derivatives were more stable when the acyl chain length of the quercetin was increased from C-16 to C-24. At pH 7.4, the derivatives formed by PLD catalysts generally were more stable than those formed by PLC catalysts. The fatty acid side chains of the derivatives retained the partial structure of the lyso-PLD or PLC catalysts. While the derivatives were more stable at pH 7.4 than at neutral pH, they showed greater reactivity than did the quercetin molecule in the decomposition of lipid peroxidation in a liposome system. At pH 7.4, PLC catalysts increased the solubility of quercetin in a mixed solution of DMPC-TMA (1,2-dimyristoyl-sn-glycero-3-phosphatidylcholine-triethylamine) at pH 7.4 in a neutral solution, while PLD catalysts did not.Inequality and health: a review.
The paper reviews studies of the relationship between inequalities in health and socioeconomic conditions and examines the conceptual
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