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Firefox Browser (Latest Version) Latest Version 2020 – Mozilla Firefox Browser. Free Download Latest Version 2020 – Firefox Browser (Latest Version) (2020).Friedel–Crafts acylation

The Friedel–Crafts acylation (or more properly Friedel-Ansatz, ), often simply called the Friedel–Crafts reaction, is the addition reaction of a hydrocarbon to a carbonyl group. The reaction was first described in the German by Friedrich August Kekule in 1894.

This reaction is synonymous with the term ‘alkylation’ but the term ‘Friedel–Crafts reaction’ is preferred by some authors and is often used as a designation of the reaction.

The reaction was first discovered by Friedel at about the same time that Kekule first reported his ketene dimerization discovery. Friedel published his paper on this reaction in 1895 and it was derived from his earlier work in which he had shown that many carbonyls can be converted to alkyl halides via a number of halogenation catalysts. The Friedel–Crafts reaction was first described in detail in a paper by G. Ansatz & D. Crafts in 1897. In this paper, the reaction was explained as a result of the carbocation generated by the addition of the organocopper to the carbonyl.

Unsymmetrical Friedel–Crafts reaction

An example of a Friedel–Crafts reaction from the non-trivial case of an alkyl group on one side of the carbonyl group (generally the alkyl group is on the carbonyl) is called an unsymmetrical Friedel-Crafts reaction. This reaction can be performed on symmetrical alkyl halides as well;

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